Hojicha is low in caffeine because it is roasted: the line turns up on packets and in front of the shelf. The reason attached is usually heat. High heat drives it off, or it sublimes and escapes. Said out loud, it sounds plausible enough.

What follows looks at how much roasting removed, which temperatures were recorded, the temperature band still left open, and where the missing part went.

Roasted deep, a little less

As the roaster's drum turns, a thin, toasty smoke drifts out. Within the published trials, roasting does not cut caffeine by much.

In a prefectural tea station's report, the light roast barely fell at all. The dark roast came out a few per cent to just over a tenth lower than before roasting.

What caused that fall, though, cannot be read out of the report. Next comes what the trial actually recorded.

Air and rotation, recorded

Hot air blows out of the roaster's mouth. What was recorded is the temperature of that outgoing air and the speed of the drum, nothing more.

The roasting ran in two stages, and the air at the second stage was the same for light and dark. What separated them was the drum's speed. The slower it turns, the longer the leaf stays inside.

How hot the leaf itself became is written nowhere. After the air comes a record from higher temperatures.

High heat inside an oven

Open an oven door and dry heat meets the face. Even an old record of longer heating at higher temperatures shows caffeine barely changing.

In a report that heated unrefined green tea in a constant-temperature oven, amino acids, vitamin C and sugars fell sharply. Caffeine, by contrast, hardly differed, the text says.

But the air leaving a roaster and the inside of an oven are measured in different places. The two records do not sit on one ruler. Next comes the band of real roasting temperatures.

A band still left open

Where bōcha is roasted, the inside of the drum runs far hotter. No public data has measured caffeine in that band.

An experiment roasting bōcha in a drum set the inner surface to around two hundred degrees, on manufacturers' advice. No public data measuring caffeine at those temperatures turned up in this search.

The sublimation temperature so often quoted is not in the official chemistry database either. The sources go as far as this: the band is still open. Next come stems before roasting, and coffee.

Stems, and coffee's split answer

Shake a packet of kukicha and the thin stems rustle. Unroasted stem tea looks lower than leaf, but the figure was not a like-for-like comparison of leaf and stem.

In the same station's table, unroasted stem tea came to about three quarters of first-flush tea. That table, though, adds one line for stems to a run of tea seasons; it was not built to compare leaf with stem.

For coffee, the same question splits. One study found the darker roast lower with brewing held level, and higher with extraction yield held level. Raw material and brewing differ, so it cannot be carried across to hojicha. Only the shape is shared: change what is held steady, and the answer changes.

Last comes where the missing part went.

Where the missing part went

Spread the roasted leaf on a sieve and fine dust gathers underneath. Where the part lost at the dark roast went is still not known.

Broken down by heat, or crumbled and lost as dust: the report does not say. Through the roasting, it was caffeine that stayed largely still. The other compounds that do move are taken one at a time in the pieces on roast depth.

On the mechanism, the sources go this far and no further. The figures and trial conditions are gathered just below. The leaf on the sieve is still faintly warm.

The numbers in detail

The trial
The trial is “Roasting Level and the Quality of Hojicha” (research period FY2013–2014), Tea Research Station, Kochi Prefectural Agricultural Technology Center. Roast level was varied on an automatic continuous hojicha roaster.
Caffeine
Caffeine is from the 2014 data (Tables 3 and 4), indexed to aracha at 100. First-flush tea: light 101, dark 94; karibancha: light 99, dark 87. The summary: the light roast barely falls, the dark fell by 6 to 13%.
Roasting conditions
Roasting ran in two stages: first at 90°C exhaust with the drum at 22 rpm, then at 100°C exhaust. The caffeine tables have two levels; second-stage rotation was 17 rpm for light, 10 for dark.
Catechin tables
The 2013 tables in the same report, which carry catechins, have three levels, light, medium and dark. First-flush tea ran at 17, 12 and 8 rpm, conditions separate from the caffeine tables. Only exhaust temperature and rotation speed are recorded.
Oven heating
A 1981 report heated green tea aracha in a forced-hot-air electric constant-temperature oven. Oven temperatures were 130°C and 160°C, 30 minutes each. Amino acids, vitamin C and free reducing sugars fell markedly.
Bōcha temperatures
The 2020 bōcha experiment set the drum's inner surface to 180°C, 200°C and 220°C, on manufacturers' advice.
Sublimation
The NIST chemistry database gives a melting point of 236.2°C and measured enthalpies of sublimation. The often-quoted sublimation temperature is not listed.
Stem tea
Unroasted kukicha came to 77% of first-flush tea in the same station's measurement. Table 3 adds one line for kukicha to a run of tea flushes; it is not a leaf-against-stem value.
Coffee
The coffee example is a 2024 study of filter coffee. With brewing held level the darker roast came out lower; with extraction yield held level, higher.